STUDY OF SOLUBILITY OF CO(NH2)2 - HOOC - COOH · NH2C2H4OH - H2O SYSTEM

Authors

  • Bakhtiyor Akhmedov Samarkand State University named after Sharof Rashidov
  • Zhamshid Shukhurov Institute of General and Inorganic Chemistry Academy of Sciences of the Republic of Uzbekistan Tashkent
  • Ilkhom Abdurakhmanov 1 Samarkand State University named after Sharof Rashidov Samarkand
  • Rizamat Begmatov Samarkand State University named after Sharof Rashidov

DOI:

https://doi.org/10.59957/jctm.v59.i3.2024.3

Keywords:

insecticide, physiologically active substance, solubility diagram, “composition-property”, urea, monoethanolammonium oxalate, ureamonoethanolammonium oxalate, rheological property, X-ray phase analysis

Abstract

In this work, the interaction of components in the CO(NH2)2 - HOOC - COOH ·NH2C2H4OH - H2O system was studied by visual polythermic method in the temperature range from -11.2 to 61°C. A polythermal solubility diagram of the system was constructed and the crystallization sites of ice, urea, monoethanolammonium oxalate, and the new phase ureamonoethanolammonium oxalate were determined.
During the addition of monoethanolammonium oxalate to urea solutions of different concentrations, changes in rheological properties (pH, density, refractive index, viscosity) were recorded, and the results were found to be consistent with the polythermal solubility diagram. A new phase formed during the study of the CO(NH2)2 - HOOC-COOH · NH2C2H4OH - H2O system, ureamonoethanolammonium oxalate, was isolated and analyzed by confirmed using appropriate analytical methods (IR, Thermal, X-ray phase).

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Published

2024-05-07

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Articles