CHEMICAL COMPOSITION AND OPTICAL PROPERTIES OF REFINED SUNFLOWER OIL WITH ADDED VARIOUS OILS

Authors

  • Galia Gentscheva Medical University-Pleven, Department of Chemistry and Biochemistry
  • Nadezhda Petkova University of Food Technology Department of Organic Chemistry and Inorganic Chemistry
  • Krastena Nikolova Medical University-Varna Department of Physics and Biophysics
  • Aleksandar Pashev Medical University-Pleven, Department of Chemistry and Biochemistry
  • Albena Predoeva National Institute of Forensic Science
  • Tinko Evtimov University of Quebec in Outaouais Photonics Research Center
  • Ina Yotkovska Medical University-Pleven, Department of Chemistry and Biochemistry

DOI:

https://doi.org/10.59957/jctm.v59.i4.2024.1

Keywords:

sunflower oil with additives, fluorescence, IR spectra, elements

Abstract

Some physicochemical characteristics and elemental composition of refined sunflower oil, as well as linseed oil added to it, were investigated; linseed oil and olive oil; truffle oil and rosemary oil. Fatty acid analysis shows substantial increases in monounsaturated fatty acids with the addition of truffle and rosemary oils (up to about 78 %).

With the same supplements, a significant oxidative stability over 20 hours was also observed. High concentrations of chlorophyll were found with the addition of rosemary oils and oils of linseed oil and olive oil. β-carotene was affected three to six times in all supplements compared to the commonly refined oil. Eight elements (Mg, Cr, Mn, Zn, Ni, As, Pd and Cd) were analyzed in the studied oils, no presence of toxic elements As and Cd (< 0.02 mg kg-1), lead was up to 0.04 mg kg-1. The remaining elements vary in different concentrations depending on the additive oils used. The fluorescence spectra of the tested samples were obtained for excitation wavelengths of 380 nm, and the fluorescence maxima allowed to determine the relationship between the optical and chemical properties of the samples. In addition, infrared spectroscopic experiments (ATR and transmittance) were used to investigate the fatty acid profile of the analyzed oil samples.

Downloads

Published

2024-07-05

Issue

Section

Articles