PHASE COMPOSITION AND MICROMORPHOLOGY OF POLYPHASE DIOPSIDE-BEARING MATERIALS

Authors

  • Bojidar Jivov Bulgarian Academy of Sciences, Institute of Metal Science, Equipment and Technologies with Hydro- and Aerodynamics Centre “Acad. A. Balevski”, 67 “Shipchenski Prohod” Blvd, 1574 Sofia, Bulgaria
  • Momchil Dyulgerov Department of Mineralogy, Petrology and Economic Geology, Faculty of Geology and Geography, Sofia University “St Kliment Ohridski”, 15 Tsar Osvoboditel Blvd, 1504 Sofia, Bulgaria
  • Vladimir Petkov Bulgarian Academy of Sciences, Institute of Metal Science, Equipment and Technologies with Hydro- and Aerodynamics Centre “Acad. A. Balevski”, 67 “Shipchenski Prohod” Blvd, 1574 Sofia, Bulgaria
  • Mihaela Aleksandrova Bulgarian Academy of Sciences, Institute of Metal Science, Equipment and Technologies with Hydro- and Aerodynamics Centre “Acad. A. Balevski”, 67 “Shipchenski Prohod” Blvd, 1574 Sofia, Bulgaria
  • Gabriel Peev Bulgarian Academy of Sciences, Institute of Metal Science, Equipment and Technologies with Hydro- and Aerodynamics Centre “Acad. A. Balevski”, 67 “Shipchenski Prohod” Blvd, 1574 Sofia, Bulgaria

DOI:

https://doi.org/10.59957/jctm.v60.i5.2025.6

Keywords:

silicate melt, polyphase materials, diopside

Abstract

Based on natural carbonate raw materials, oxide components and fluorite, polyphase materials with a silicate composition were synthesized in laboratory conditions. The phase composition, structure and micromorphology of the obtained experimental samples were studied. Their textural properties - medium to micro-grained, spinifex or chilled marginal zones, attest that they have crystalized from a melt. In separate areas, gradual transitions from one type of texture to another and a limited presence of amorphous zones were observed. The diopside is the main phase that appear in all samples as prismatic to needle-shaped crystals. Fluorite presents in small amount in all samples with spheroidal to irregular shape. Wollastonite, akermanite, calcite and quartz also present as important phases according to sample’s composition. Zincian hydroxide, chromite and an unidentified pigment are small constituents and reflect addition of various metals as colorants.

Author Biography

Momchil Dyulgerov, Department of Mineralogy, Petrology and Economic Geology, Faculty of Geology and Geography, Sofia University “St Kliment Ohridski”, 15 Tsar Osvoboditel Blvd, 1504 Sofia, Bulgaria

First author of the article.

References

R.B. Heimann, Classic and advanced ceramics: from fundamentals to applications, John Wiley & Sons, 2010, 573.

W. Holland, G.H. Beall, Glass-ceramic technology, 3rd ed., Wiley-American Ceramic Society, 2019.

J.E. Shelby, Introduction to glass science and technology, 3rd ed., Royal Society of Chemistry, 2020.

E. Aydin, Problems and solutions in glass production, Society of Glass Technology, 2020.

S.J. Ikhmayies, Advanced ceramics, Springer Cham, 2024.

E. Gerasimov, A. Gerasimov, A. Atanasov, V. Toshev, D. Petkov, D. Ivanov, L. Georgieva, L. Pavlova, N. Drenska, P. Vinarov, P. Petrov, S. Buchvarov, S. Panova, S. Bagarov, S. Serbezov, S. Stefanov, S. Djambasov, T. Stoikova, T. Dackova, H. Berlinov, Technology of ceramic products and materials, S. Buchvarov (Eds.), IK Sarasvati, Sofia, 2003, (in Bulgarian).

R. Danzer, T. Lube, R. Damani, Ceramics science and technology, Set. Adv. Eng. Matt. 10, 4, 2008, pp. 275-298.

D.W. Richerson, W.E. Lee, Modern ceramic engineering: properties, Processing and Use in Design, 4th ed., CRC press, 2018.

C.B. Carter, M.G. Norton, Ceramic materials: science and engineering, Springer New York, NY, 2016.

K.P. Misra, R.D.K. Misra (Eds.), Ceramic science and engineering, Elsevier, 2022.

R.A. Youness, D.M.T. Eldeen, M.A. Taha, A review on calcium silicate ceramics: properties, limitations, and solutions for their use in biomedical applications, Silicon, 15, 2023, 2493-2505.

S. Wu, M. Chen (Eds.), Silicate building materials SBM 2013, 1st ed., Trans Tech Publications, 2014.

M.B. Revuelta, Construction materials, geology, production and applications, Springer Cham, 2021, 602.

A.K. Chatterjee, Cement production technology, principles and practice, 1st ed., Imprint CRC Press, Boca Raton, 2018, 439.

C. Yang, F. Zhou, Q. Chen, G. Shi, M. Kaziana, M. Gasper, Development and application of modern building ceramic materials, Res. Applic. Mater. Sci., 5, 2, 2023, 25-32.

S.A.M. Abdel-Hameed, Development of wall-covering glass-ceramics from raw materials, Glass Sci. Technol., 75, 6, 2002, 290-293.

S.A.M. Abdel-Hameed, Thermal and chemical properties of diopside-wollastonite glass-ceramics in the SiO2 - CaO - MgO system from raw materials, Ceram. Int., 2003, 29, 265-269.

J. Feng, D. Wu, M. Long, K. Lei, Y. Sun, X. Zhao, Diopside glass-ceramics were fabricated by sintering the powder mixtures of waste glass and kaolin, Ceram. Int., 48, 2022, 27088-27096.

L.S. Bozadzhiev, R.L. Bozadzhiev, L.S. Doncheva, Synthetic diopside, Qualicer, 3, 2006, 89-92.

L.S. Bozadjiev, R.L. Bozadjiev, G.T. Georgiev, L.S. Doncheva, Diopside porcelain tile, Am. Ceram. Soc. Bull., 85, 12, 2006, 9101-9103.

L. Bozadjiev, L. Doncheva, Methods for diopside synthesis, J. Chem. Technol. Metall., 41, 2, 2006, 125-128.

R. Bozadzhiev, Wollastonite and diopside - ceramic raw materials, J. Manag. Educ., 4, 2, 2008, 205-209, (in Bulgarian).

R. Titorenkova, T. Dimitrov, Y. Tzvetanova, Synthesis and characterization of Cr-doped diopside ceramics, Rev. Bul. Geol. Soc., 83, 3, 2022, 47-50.

B.N. Sherikar, B. Sahoo, A.M. Umarji, One-step synthesis of diopside (CaMgSi2O6) ceramic powder by solution combustion method, Adv. Powder Technol., 31, 8, 2020, 3492-3499.

R. Titorenkova, V. Kostov-Kytin, Ts. Dimitrov, Synthesis, phase composition and characterization of Co-diopside ceramic pigments, Ceram. Int., 48, 24, 2022, 36781-36788.

T. Dimitrov, R. Titorenkova, O. Petrov, Diopside ceramic pigments obtained by a sol-gel method with the participation of different chromophore elements, Proceedings of University of Ruse Angel Kanchev, 61, 10.1., ISSN: 2603-4123, 2022, 74-79.

Downloads

Published

2025-09-03

Issue

Section

Articles