GLASS-FORMING REGION IN THE GeSe2-In2Te3-GeTe SYSTEM AND SOME PHYSICOCHEMICAL PROPERTIES OF GLASSY ALLOYS
DOI:
https://doi.org/10.59957/jctm.v61.i3.2026.12Keywords:
glass-forming region, chalcogenide glasses, thermal properties, thermomechanical properties, density, microhardnessAbstract
For the first time, chalcogenide glasses from the GeSe2-In 2Te3-GeTe system are synthesized. Visual, X-ray diffraction, and electron microscopic investigations identify the glass-forming area, primarily located in the GeSe2-rich region.
Differential thermal analysis determines the characteristic temperatures of phase transformations, including the glass transition temperature (Tg), crystallization temperature (Tcr), and melting temperature (Tm). Hruby’s criterion is used to estimate the glass-forming ability (KG). The chalcogenide glasses’ density (d) and microhardness (HV) are measured. Compactness, elasticity modulus, and thermomechanical characteristics (micro-void volume (Vh) and formation energy (Eh)) are computed using the acquired properties. A thorough discussion and link between the glasses’ properties and composition are established.
References
V.S. Minaev, Stekloobraznie poluprovodnikovie splavi, Metalurgia, Moskva, 1991, 26 (in Russian).
Applications of Chalcogenides: S, Se, and Te, Ed. Gurinder Kaur Ahluwalia, Springer, Springer International Publishing, Switzerland 2017, 39.
D. Pavlov, M. Dimitrov, G. Petkova, H. Giess, C. Gnehm, J. Electrochem. Soc., 142, 1995, 2919.
R. Kemparaju, Rohit, Akila Prabhudesai, S. Charan Prasanth, M. Madesh Kumar, K. Ramesh, Electrical switching and phase change properties of GeTe-Al2Te3 chalcogenide alloys, Ceramics International, 2025, Available online 12 April 2025, https://doi.org/10.1016/j.ceramint.2025.04.110.
S. Asokan, K.P. Lakshmi, Electrical Switching and Other Properties of Chalcogenide Glasses, Journal of the Indian Institute of Science, 91:2, 319-330.
K. Ramesh, Pumlinmunga, R. Venkatesh, N. Naresh, E.S.R. Gopal, Phase change properties of chalcogenide glasses – some interesting observations, Key Engineering Materials, 702, 37-42.
N. Ciocchini, M. Laudato, M. Boniardi, E. Varesi, P. Fantini, A. L. Lacaita, D. Ielmini, Bipolar switching in chalcogenide phase change memory, Sci Rep, 6, 2016, 29162.
Achamma George; D. Sushama; S. Asokan, Electrical Switching Studies of Bulk Ge‐Te‐In Chalcogenide Glasses, AIP Conf. Proc., 1391, 2011, 778–780.
J.S. Sanghera, I.D. Aggarwal, Active and passive chalcogenide glass optical fibers for IR applications: a review, J. Non-Cryst. Solids, 256–257,1999, 6-16
J. Sanghera, D. Gibson, 5 - Optical properties of chalcogenide glasses and fibers, Editor(s): Jean-Luc Adam, Xianghua Zhang, Chalcogenide Glasses, Woodhead Publishing, 2014, 113-138.
R. Paschotta, Mid-infrared Fibers, in the RP Photonics Encyclopedia, retrieved 2025-06-12, https://doi.org/10.61835/0nz
Bruno Bureau, Catherine Boussard-Plédel, Shuo Cui, Radwan Chahal, Marie-Laure Anne, et al., Chalcogenide optical fibers for mid-infrared sensing, Optical Engineering, 53, 2, 2014,027101/1-027101/7.
J. Troles, G. Renversez, Chalcogenide microstructured optical fibers: fabrication and applications, 24th International Conference on Transparent Optical Networks (ICTON), Bari, Italy, 2024, doi: 10.1109/ICTON62926.2024.10647513.
J. Nishii, S. Morimoto, R. Yokota, T. Yamagishi, Transmission loss of Ge-Se-Te and Ge-Se-Te-Tl glass fibers J. Non-Cryst. Solids, 95-96, 2, 1987, 641-646.
A.R. Hilton, D.J. Hayes, M.D. Rechtin, Infrared absorption of some high-purity chalcogenide glasses, J. Non-Cryst. Solids, 17, 3, 1975, 319-338.
T. Katsuyama, H. Matsumura, J. Appl. Phys., 75, 1994, 2743.
J. Olivier-Fourcade, A. Bouaza, J.C. Jumas, M. Maurin, J. Non-Cryst. Solids, 111, 1989, 277.
V. Vassilev, G. Vassilev, E. Fidancevska, Chalcogen. Lett., 5, 12, 2008, 415.
S. Surinach, M.D. Baro, M.T. Clavaguera-Mora, N. Clavaguera, Thermochimica Acta, 133, 1988, 287.
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