STUDYING THE SOLUBILITY OF THE ZINC SULFATE - AMMONIUM NITRATE - WATER SYSTEM
DOI:
https://doi.org/10.59957/jctm.v61.i3.2026.4Keywords:
Ammonium nitrate, zinc sulfate, NH4NO3·ZnSO4·3H2O, visual polytherm, X-ray phase analysis, IR spectrumAbstract
The solubility of the components in the ZnSO4 - NH4NO3 - H2O system was studied by the visual-polythermal method in the temperature range from -19.4°С to +13.0°С. The phase diagram delimits the fields of ice crystallization, NH4NO3, NH4NO3·ZnSO4·3H2O, and ZnSO4. A solubility diagram was constructed, and a new compound NH4NO3·ZnSO4·3H2O was separated. The new compound was identified by scanning electron microscopy (SEM), chemical, X-ray phase, and IR spectroscopic analysis.
References
REFERENCES
J. Osredkar, N. Sustar, Copper and zinc, biological role and significance of copper/zinc imbalance, J. Clinic Toxicol s., 3, 2161, 2011, 0495.
C.M. Morton, H. Pullabhotla, L. Bevis, D.B. Lobell, Soil micronutrients linked to human health in India //Scientific Reports. – 2023. – Т. 13. – №. 1. – С. 13591. https://doi.org/10.1038/s41598-023-39084-8
Z. Turaev, I.T. Shamshidinov, I.I Usmanov, Sh.M. Mamadaliyev, Study of the interaction of sulfates of copper, zinc and cobalt with monocalcium phosphate at 30 and 80°C, Univ.: chem. biol., 1, 67, 2020, 21-25, https://7universum.com/ru/nature/archive/item/8611, (in Russian).
Tripathi D. K. et al. Micronutrients and their diverse role in agricultural crops: advances and future prospective //Acta Physiologiae Plantarum. - 2015. - Т. 37. - С. 1-14, https://doi.org/10.1007/s11738-015-1870-3
I. Zewide, A. Sherefu, Review paper on effect of micronutrients for crop production, J. Nutr. Food Process, 7, 4, 2021, 1-8, https://DOI:10.31579/2637-8914/063
K.O. Soetan, C.O. Olaiya, O.E. Oyewole, The importance of mineral elements for humans, domestic animals and plants: A review, Afr. J. Food Sci., 5, 4, 2010, 200-222.
A.K. Shukla, S.K. Behera, A. Pakhe, S.K. Chaudhari, Micronutrients in soils, plants, animals and humans, Indian J. Fert., 3, 14, 2018, 30-54.
D.K. Tripathi, S. Singh, S. Singh, S. Mishra, D.K. Chauhan, N.K. Dubey, Micronutrients and their diverse role in agricultural crops: advances and future prospective, Acta Physiol. Plant., 37, 2015, 1-14, https://doi.org/10.1007/s11738-015-1870-3
F.SH. Nazarova, N.E. Djumanova, B.N. Toshmamatov, Sh.O. Korzhavov, Z.A. Abduraimov, BIOLOGICAL ROLE OF MICROELEMENTS AND THEIR CONTENT IN EPIDERMAL FORMATIONS, // Eur. J. Mol. Clin. Med., 2, 8, 2021, 1675-1687, https://doi.org/10.1134/S2079086422020104
V. Nandal, M. Solanki, The Zn as a vital micronutrient in plants // J. Microbiol. Biotechnol. Food Sci., 3, 11, 2021, e4026.
M.R. Islam, S. Akash, M.H. Jony, M.N. Alam, F.T. Nowrin, M.M. Rahman, A. Rauf, M. Thiruvengadam, Exploring the potential function of trace elements in human health: a therapeutic perspective, Mol. Cell. Biochem., 10, 478, 2023, 2141-2171, https://doi.org/10.1007/s11010-022-04638-3
I. Michalak, A. Saeid, K. Chojnacka, M. Gramza, Trace elements as fertilizer micronutrients, Recent Adv. Trace Elem., 2018, 299-318, https://doi.org/10.1002/9781119133780.ch15
I. Kostova, Biological and Medical Significance of Chemical Elements, Bentham Science Publishers, 2023.
M. Imtiaz, R. Abdul, P. Khan, M.Y. Memon, M. Aslam, The role of micronutrients in crop production and human health, Pak. J. Bot., 42, 4, 2010, 2565-2578.
H.S. Jatav, L.D. Sharma, S.K. Singh, V.D. Rajput, M. Parihar, S.S. Jatav, D. Jinger, S. Kumar, Sukirti, An overview of micronutrients: prospects and implication in crop production, Plant micronutrients: deficiency and toxicity management. – 2020. – С. 1-30.
M.A. Oliver, P.J. Gregory, Soil, food security and human health: a review, Eur. J. Soil Sci., 66, 2, 2015, 257-276, https://doi.org/10.1111/ejss.12216
A.G. Assunção, I. Cakmak, S. Clemens, M. González-Guerrero, A. Nawrocki, S. Thomine, Micronutrient homeostasis in plants for more sustainable agriculture and healthier human nutrition, J. Exp. Bot., 73, 6, 2022, 1789-1799, https://doi.org/10.1093/jxb/erac014
D. Makhkamova, Z. Turayev, B. Kucharov, Research on the effect of microelement salt with fertilizer, //E3S Web Conf., EDP Sci., 486, 2024, 01012.
D.N. Makhkamova, Z. Turayev, STUDYING THE SOLUBILITY OF THE SYSTEM ZnSO4-KNO3-H2O, J. Chem. Tech. Metall., 59, 1, 2024, 137-144, https://doi.org/10.59957/jctm.v59.i1.2024.16
T.W. Cornelius, S. Grigorian, X-ray Diffraction of Functional Materials, Eds. T. W. Cornelius, S. Grigorian, Basel: MDPI AG, 2022.
A.A. Bunaciu, H.Y. Aboul-Enein, V.D. Hoang, Vibrational spectroscopy applications in biomedical, pharmaceutical and food sciences, Elsevier, 2020.
A.S.Trunin, D.G.Petrova,Visual-polythermal method, Kuibyshev, KPU, 1977. (in Russian)
M.I. Gasik, V. Dashevskii, A. Bizhanov, Ferroalloys: Theory and Practice. – Cham : Springer, 2020.
P. Malhotra, Analytical Chemistry: Basic techniques and methods, Cham: Springer, 2023.
Downloads
Published
Issue
Section
License
Copyright (c) 2026 Journal of Chemical Technology and Metallurgy

This work is licensed under a Creative Commons Attribution-NonCommercial 4.0 International License.