OPTIMIZING THE COMPOSITION OF UNPLASTICIZED POLYVINYL CHLORIDE PROFILES BY ADDING CHLORINATED POLYETHYLENE

Authors

  • Petranka Naydenova-Marinova University of Chemical Technology and Metallurgy
  • Danika Aleksandrova University of Chemical Technology and Metallurgy

DOI:

https://doi.org/10.59957/jctm.v61.i3.2026.6

Keywords:

unplasticized polyvinyl chloride, modification, properties, chlorinated polyethylene.

Abstract

The synergistic effect of partial replacement of acrylic modifier with chlorinated polyethylene on the performance properties of extruded profiles made of rigid polyvinyl chloride was studied. Five dryblend formulations with different ratios of chlorinated polyethylene and acrylic modifier were prepared. Profiles with identical geometry (five-chamber frame) were extruded from them. Test specimens were prepared from the surface of the profiles. Tests were conducted and the physicomechanical properties of the tested samples were analysed. Based on this, the optimal content of chlorinated polyethylene in the dryblend composition was established. The impact and cold resistance, linear expansion, strength of the weld (thermally sealed corner), gloss and whiteness of the products were studied on the modified profiles. The aim of the present work is to improve the performance properties and reduce the cost of the final products by modifying the composition of the dryblend to produce profiles made of unplasticized polyvinyl chloride.

References

Poly(vinyl chloride) (PVC): an updated review of its properties, polymerization, modification, recycling, and applications, J. Mater. Sci., 59, (2024), pp. 21605–21648;

X. Wang, J. Zhang, H. Chen, Comparison of toughening effects of several common toughening agents and polycarbonate-polydimethylsiloxane block copolymer on polyvinyl chloride, Polym. Adv. Technol., 34 (2023), pp. 1844-1855;

J. Chang, M. Jin, B. Wang, Y.-H. Hu, W.J. Zheng, Study on mechanical properties of PVC modified by new core-shell toughener, J. Phys. Conf. Ser., 2459 (2023), 10.1088/1742-6596/2459/1/012042, https://api.semanticscholar.org/CorpusID:257802047;

A. Cross, R.N. Haward, Thermal fracture of plastics, J. Polym. Sci. Polym. Phys. Ed., 11 (1973), pp. 2423-2439;

N. Walker, R.N. Haward, J.N. Hay, Plastic fracture in poly (vinyl chloride), J. Mater. Sci., 14 (1979), pp. 1085-1094;

Acrylic Impact Modifiers, https://akdenizchemson.com/products/acrylic-impact-modifiers;

P. Bilym, S. Zolotov, P. Firsov, S. Amir, H. Kais, Research of the polymer modifier functions in the realization of improved operational properties of acrylic adhesive compositions, AIP Conf. Proc, AIP Publishing (2023);

S.H.H. Kakhk, J.K. Rad, H. Abedini, A.R. Mahdavian, Thermomechanical study on toughened PVC with an impact modifier based on the acrylonitrile-styrene-acrylate core-shell particles, Polymer (Guildf)., 290 (2024), Article 126545;

Z. Zhang, S. Wang, J. Zhang, W. Zhu, T. Tian, Remarkably improved toughness and thermal stability of poly (vinyl chloride) (PVC)/ poly (α-methylstyrene-acrylonitrile)(α-MSAN) blend with the assistance of two impact modifiers, Polym. Test., 51 (2016), pp.1-5;

Elina Kimya, CPE And Impact Modifiers, https://www.elinakimya.com/;

Atman polymer, https://www.atmanpolymer.com/en/blog/chlorinated-polyethylene;

Chlorinated Polyethylene (Cpe) Versus All Acrylic Impact Modifiers for C-pvc Pipesр Yashodhan Kanadeр on July 9, (2022);

https://bds-bg.org/bg/project/show/bds:proj:113654

Downloads

Published

2026-05-01

Issue

Section

Articles