SYSTEMATIC APPROACH TO DESCRIBING STEEL REFINING PROCESSES IN A LADLE FURNACE
DOI:
https://doi.org/10.59957/jctm.v61.i3.2026.16Keywords:
steel, ladle furnace, metal–slag system, metal–additive system, element distribution coefficients, interatomic interaction, Harrington's desirability function, chemical composition predictionAbstract
This work presents a systematic approach to describing the physicochemical processes occurring in the metal-slag system during steel refining in a ladle furnace. The aim of the study was to develop methods for predicting the distribution of main and impurity elements based on a comprehensive analysis of the initial and final melts of metal and slag. Industrial data on the chemical composition of SAE1006 grade steel and the corresponding slag were used as the input. Based on the methodological framework of the Directed Chemical Bonding Concept (DCBC) and mathematical processing of multivariate data, the applicability of interatomic interaction parameters and technological regime indicators as model parameters was substantiated. Complex indicators for the metal-slag and metal-additive systems were constructed using Harrington’s desirability function, which enables integration of multidimensional parameters into a single generalized index. Analytical dependencies were developed for calculating the distribution coefficients of sulphur (S), silicon (Si), manganese (Mn), and aluminium (Al), considering both the composition of metallurgical phases and the smelting conditions. The proposed approach provides a quantitative assessment of the distribution coefficients of elements as variable quantities, which fundamentally distinguishes it from traditional methods. The results obtained form the basis for developing algorithms to predict the chemical composition of the final melt and for creating practical recommendations on the selection of optimal additives and slag-forming mixtures aimed at improving steel quality and reducing production costs.
References
A. Harada, N. Maruoka, H. Shibata, S. Kitamura, A Kinetic Model to Predict the Compositions of Metal, Slag and Inclusions during Ladle Refining: Part 1, Basic Concept and Application, ISIJ International, 53, 2013, 2110-2117, https://doi.org/10.2355/isijinternational.53.2110.
D. Jochymczyk, M. Warzecha, F. Hutny, Industrial Investigations of S355 Steel-Grade Homogenization in a 100-Tonne Ladle Furnace, Materials (Basel), 2025, 18(1):180, https://doi.org/10.3390/ma18010180.
D. You, S.K. Michelic, C. Bernhard, (2020), Modeling of Ladle Refining Process Considering Mixing and Chemical Reaction, steel research int., 91, 2020, 2000045. https://doi.org/10.1002/srin.202000045.
Z. Deng, M. Zhu, Deoxidation Mechanism of Al-Killed Steel during Industrial Refining Process, ISIJ International, 54, 2014, 1498-1506, https://doi.org/10.2355/ isijinternational. 54.1498.
U. Mitra, T.W. Eagar, Slag-metal reactions during welding: Part II. Theory. Met. Trans., 22, 1991, 73–81, https://doi.org/10.1007/bf02672529.
R. Ceccolini, U. Martini, S. Rinaldi, S. Neri, A. Schino, Effect of slag control on steel process optimization and on environment, Journal of Materials and Environmental Science, 8, 2017, 2403.
M.I. Mendelev, S. Han, D.J. Srolovitz, G. Ackland, D. Sun, M. Asta, Development of new interatomic potentials appropriate for crystalline and liquid iron, Philosophical Magazine, 83, 2003, 3977-3994, https://doi.org/10.1080/14786430310001613264.
L. Bolʼshov, S. Korneichuk, E. Bolʼshova, Wagner coefficient of interaction between hydrogen and nickel in liquid steel, Izvestiya Ferrous Metallurgy, 65, 2022, 519-525, https://doi.org/10.17073/0368-0797-2022-7-519-525.
L. Zhang, S. Sun, S. Jahanshahi, Molecular Dynamics Simulations of Silicate Slags and Slag–Solid Interfaces, Journal of Non-Crystalline Solids, 282, 2001, 24-29, https://doi.org/10.1016/S0022-3093(01)00325-8.
D. Togobitska, A. Belkova, New approach to evaluating the thermodynamic consistency of melts in the Metal-Slag system based on interatomic interaction parameters, Lithuanian Journal of Physics, 64, 1, 2024, 58-71, https://doi.org/10.3952/physics.2024.64.1.6.
G. Stovpchenko, D. Togobitskaya, L. Lisova, D. Stepanenko, L. Medovar, Predictive models for molten slags viscosity and electrical conductivity based on directed chemical bonds concept, Ironmaking & Steelmaking, 49, 2022, 1-9, https://doi.org/10.1080/03019233.2022.2026043.
D. Stepanenko, O. Grishin, A. Bielkova, Analitical and experimental studies of properties of slag and slag-forming mixtures of steelmaking production, Fundamental and applied problems of ferrous metallurgy, 37, 2023, 260-270, (in Ukraine), https://doi.org/ 10.52150/2522-9117-2023-37-260-270.
D.Togobitska, A. Bielkova, D. Stepanenko Model decision-making system in the task of choosing the optimal composition of the blast furnace burden under specific operating conditions of BF, Acta Metallurgica Slovaca, 29(2), 2023, 67–74, https://doi.org/10.36547/ams.29.2.1764.
E. C. Harrington, The desirable function, Industrial Quality Control, 21 (10), 1965, 494-498.
D.M. Togobytska, I. R. Povorotnia, V.P. Piptyuk, & O. V. Kuksa, Comprehensive assessment of the properties of additives as a necessary component of the intelligent decision-making system in the proofing of steel at the ladle-furnace installation, Fundamental and applied problems of ferrous metallurgy, 38, 2024, 292-307, (in Ukraine), https://doi.org/10.52150/2522-9117-2024-38-292-307.
Downloads
Published
Issue
Section
License
Copyright (c) 2026 Journal of Chemical Technology and Metallurgy

This work is licensed under a Creative Commons Attribution-NonCommercial 4.0 International License.