CHARACTERIZATION ASSESSMENT OF COLUMBITE ORE FOR NIOBIUM PENTOXIDE VALUE ADDITION FOR ORTHOPEDIC APPLICATION
DOI:
https://doi.org/10.59957/jctm.v61.i4.2026.17Keywords:
Niobium pentoxide; Columbite; Magnetic Separation; Orthopedic; Kuru MinesAbstract
The demand for stable source for niobium pentoxide has market prospects for orthopedic implants, especially if economically sourced and processed. Columbite ore was extracted and sampled from four pits in Kuru mine site in Jos South Local Government Area, Nigeria. The columbite was processed using a three-disc rapid magnetic separator, and characterized using ED-XRFS, XRD, and SEM/EDS. The magnetic samples were mainly iron with impurities, while the ferromagnetic samples were columbite with niobium pentoxide, and the non-magnetic samples were more of silica. The crude was found to contain 32.1 % ZrO2, 3.42 % ThO2, 12.31 % Nb2O5, 6.65 % Fe2O3, 52.19 % SiO2, and 1.61 % TiO2, along with other trace compounds. The 45 A current application yielded the highest ferromagnetic product with a high grade of Niobium pentoxide, with a recovery rate of 67.67 %. The sample morphology showed coarse interlocking within crystal aggregates in the ore matrix. The elements present were Ti, Al, Mn, O, B, Ta, and Nb. The processed concentrate sample contained 1.8414 % SiO2, 13.9485 % TiO2, 20.9295 % Fe2O3, 46.5767 % Nb2O5, 7.9113 % Ta2O5, and other constituent compounds in trace form. The processed tailings sample contained 12.1418 % MgO, 4.3061 % Al2O3, 1.3150 % SO3, 40.8441 % SiO2, 4.8829 % CaO, 6.4475 % Cr2O3, 25.9409 % Fe2O3, and 1.0330 % NiO.
References
References
Alaneme, K. K., Fatokun, A. A., Oke, S. R., & Olubambi, P. A. (2020). Nanoindentation studies and analysis of the mechanical properties of Ti-Nb2O5-based composites. Manufacturing Review, 7, 19.
Marins, N. H., Lee, B. E., e Silva, R. M., Raghavan, A., Carreño, N. L. V., & Grandfield, K. (2019). Niobium pentoxide and hydroxyapatite particle-loaded electrospun polycaprolactone/gelatin membranes for bone tissue engineering. Colloids and Surfaces B: Biointerfaces, 182, 110386.
Safavi, M. S., Walsh, F., Visai, L., & Khalil-Allafi, J. (2022). Progress in niobium oxide-containing coatings for biomedical applications: a critical review. ACS omega, 7(11), 9088-9107.
Bonadio, T., Fiorentin, E., Candido, A., Miyahara, R., Freitas, V., Kiyochi Jr, H., Hernandes, L., Rosso, J., Burato, J., & Santos, I. (2020). Enhanced mechanical properties and osseointegration features of CaNb2O6–PNb9O25–Ca3 (PO4) 2 triphasic nanostructured bioceramics derived by optimized sinterization of Nb2O5 and natural hydroxyapatite-β-tricalcium phosphate. Ceramics International, 46(8), 12837-12845.
Demirkol, N. (2017). Bioactivity Properties and Characterization of Commercial Synthetic Hydroxyapatite-5 wt.% Niobium (V) Oxide-5 wt.% Magnesium Oxide Composite. Acta Physica Polonica A, 132(3), 786-788.
Alaneme, K. K., Adu, O. P., Oke, S. R., Falodun, O. E., & Olubambi, P. A. (2022). Densification characteristics, microstructure, and wear behaviour of spark plasma sintering processed titanium-niobium pentoxide (Ti-Nb2O5) based composites. Journal of King Saud University-Engineering Sciences, 34(4), 282-289.
Kiyochi Junior, H. D. J., Candido, A. G., Bonadio, T. G. M., da Cruz, J. A., Baesso, M. L., Weinand, W. R., & Hernandes, L. (2020). In vivo evaluation of interactions between biphasic calcium phosphate (BCP)-niobium pentoxide (Nb 2 O 5) nanocomposite and tissues using a rat critical-size calvarial defect model. Journal of Materials Science: Materials in Medicine, 31, 1-13.
Mohammad, N., Ahmad, R., Rosli, N. M., Manan, M. A., Marzuki, M., & Wahi, A. (2021). Sol-gel deposited hydroxyapatite-based coating technique on porous titanium niobium for biomedical applications: A mini review. Materials Today: Proceedings, 41, 127-135.
Afifi, M., El-Naggar, M. E., Muhammad, S., Alghamdi, N., Wageh, S., Abou Taleb, M. F., Mostafa, M. S., Salem, S., & El-Tantawy, I. (2022). Compositional adjusting and antibacterial improvement of hydroxyapatite/Nb2O5/graphene oxide for medical applications. Journal of Inorganic and Organometallic Polymers and Materials, 32(6), 2160-2172.
Alaneme, K. K., Ajani, I. J., & Oke, S. R. (2023). Wear behaviour of titanium-based composites reinforced with niobium pentoxide in saline and acidic environments. Heliyon, 9(2).
Silva, G. F., Tanomaru-Filho, M., Bernardi, M. I., Guerreiro-Tanomaru, J. M., & Cerri, P. S. (2015). Niobium pentoxide as radiopacifying agent of calcium silicate-based material: evaluation of physicochemical and biological properties. Clinical oral investigations, 19, 2015-2025.
Singh, R., Bathaei, M. J., Istif, E., & Beker, L. (2020). A review of bioresorbable implantable medical devices: Materials, fabrication, and implementation. Advanced Healthcare Materials, 9(18), 2000790.
Pandey, A., Awasthi, A., & Saxena, K. K. (2020). Metallic implants with properties and latest production techniques: a review. Advances in Materials and Processing Technologies, 6(2), 405-440.
Ikwuegbuenyi, C. A., Lohkamp, L.-N., Maruthanal, J., Kassim, K. O., Shabani, H., & Härtl, R. (2023). Regulation, approval, and access of spinal implants in low-middle-income countries: a narrative review and case study. Expert Review of Medical Devices, 20(12), 1173-1181.
Abere, D., Oyatogun, G., Abioye, A., Rominiyi, A., Abioye, O., Yaskuma, U., Onotu, G., Ogar, M., Oyatogun, A., & Igbonwelundu, M. (2017). Comparative study of local mining methods and assay of cassiterite with other alluvial mineral deposits in Kuru-Jantar, Plateau State, Nigeria. American Journal of Mining and Metallurgy, 4(1), 51-61.
Abraham, E. M., Onwe, M. R., Usman, A. O., Gwazah, C. A., & Uchenna, M. E. (2022). Mapping of mineral deposits within granitic rocks by aeromagnetic data—a case study from Northern Nigeria. Arabian Journal of Geosciences, 15(21), 1656.
Ebikemefa, C. E. (2020). Benefits of cassiterite mining by artisanal miners in Jos Plateau, Nigeria. Bulletin of the National Research Centre, 44, 1-8.
Alabi, O. O, Gbadamosi, Y. E and Akinpelumi, T. (2021). Desliming process of kuru columbite (Plateau state) using scrubbing method towards niobium pentoxide recovery, International Journal of Engineering Research Updates, 01(01), pp. 043–049.
Ebimobowei, E. C. (2020). Benefits of cassiterite mining by artisanal miners in Jos Plateau, Nigeria. Bulletin of the National Research Centre, 44(1).
Shikika, A., Sethurajan, M., Muvundja, F., & Mugumaoderha, M. (2020). A review on extractive metallurgy of tantalum and niobium. Hydrometallurgy, 198, 105496.
Nzeh, N. S., Popoola, P., Adeosun, S., & Adeleke, A. (2023). Characterization of Rayfield-Jos columbite deposit for efficient beneficiation and recovery of niobium and tantalum. TMS Annual Meeting & Exhibition,
Kumar, S., Nehra, M., Kedia, D., Dilbaghi, N., Tankeshwar, K., & Kim, K.-H. (2020). Nanotechnology-based biomaterials for orthopaedic applications: Recent advances and future prospects. Materials science and engineering: C, 106, 110154.
Safavi, M. S., Khalil-Allafi, J., Motallebzadeh, A., Volpini, C., Khalili, V., & Visai, L. (2023). Encouraging tribomechanical and biological responses of hydroxyapatite coatings reinforced by various levels of niobium pentoxide particles. Materials Advances, 4(22), 5618-5632.
Alabi, O. O., Akinnodi, O. B., and Gbadamosi, Y. E. (2021). Characterization of Kuru (Plateau State) Niobium Pentoxide Bearing Ore for Effective Value Addition. Proceedings of the 2021 Annual Conference of the School of Engineering and Engineering Technology, FUTA, IARASETA/21/T4002, pp. 314-327.
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